Pengaruh Rasio Molar pada Sintesis Molecularly Imprinted Polymers (MIPs) terhadap Kinerja Penyerapan Senyawa Azo Dye: Suatu Tinjauan Singkat

Yunita Dwi Larasati; Neena Zakia

doi:10.17977/um0260v8i22024p006

Authors

Yunita Dwi Larasati Departemen Kimia, FMIPA, Universitas Negeri Malang, Indonesia
Neena Zakia Departemen Kimia, FMIPA, Universitas Negeri Malang, Indonesia

DOI:

https://doi.org/10.17977/um0260v8i22024p006

Keywords:

Rasio molar, Molecularly imprinted polymers, pewarna azo

Abstract

Pemisahan perwarna azo telah banyak diteliti dan dikembangkan, karena pemisahan pewarna azo memerlukan metode yang selektif untuk memisahkannya dalam suatu matriks yang kompleks. Molecularly Imprinted Polymers (MIPs) salah satu metode pemisahan pewarna azo yang dikembangkan, MIPs merupakan polimer sintetis yang memiliki selektivitas tinggi karena terdapat rongga atau cetakan pada MIPs dengan sifat dan karakteristik yang sama terhadap senyawa target yang akan diserap dan dipisahkan. MIPs disintesis dengan menggunakan template, monomer fungsional, pengikat silang, inisiator dan pelarut porogen. Efektivitas dan selektivitas kinerja adsorpsi MIPs dalam menyerap atau memisahkan suatu senyawa azo dye tertentu salah satunya dipengaruhi oleh jenis dan rasio molar komponen yang digunakan. Hal tersebut dapat mempengaruhi nilai kapasitas pengikatan (Q) dan faktor pencetakan (IF) yang merupakan parameter kinerja suatu MIPs dapat dikatakan baik. Arah tinjauan ini adalah memberikan informasi terkait pengaruh rasio molar komponen yaitu templat:monomer:pengikat silang pada sintesis MIPs terhadap kinerja penyerapannya untuk suatu analit yaitu senyawa pewarna azo.

References

V. S. Munagapati, V. Yarramuthi, Y. Kim, K. M. Lee, and D.-S. Kim, “Removal of anionic dyes (Reactive Black 5 and Congo Red) from aqueous solutions using Banana Peel Powder as an adsorbent,” Ecotoxicol Environ Saf, vol. 148, pp. 601–607, Feb. 2018, doi: 10.1016/j.ecoenv.2017.10.075.

S. Salahi, M. Parvini, and M. Ghorbani, “Equilibrium Studies in Adsorption of Hg(II) from Aqueous Solutions using Biocompatible Polymeric Polypyrrole-Chitosan Nanocomposite,” Polycycl Aromat Compd, vol. 34, no. 3, pp. 225–236, May 2014, doi: 10.1080/10406638.2014.886077.

G. Wulff, A. Sarhan, and K. Zabrocki, “Enzyme-analogue built polymers and their use for the resolution of racemates,” Tetrahedron Lett, vol. 14, no. 44, pp. 4329–4332, Jan. 1973, doi: 10.1016/S0040-4039(01)87213-0.

L. M. Madikizela, P. S. Mdluli, and L. Chimuka, “Experimental and theoretical study of molecular interactions between 2-vinyl pyridine and acidic pharmaceuticals used as multi-template molecules in molecularly imprinted polymer,” React Funct Polym, vol. 103, pp. 33–43, Jun. 2016, doi: 10.1016/j.reactfunctpolym.2016.03.017.

C. Liu, L. Shang, H.-T. Yoshioka, B. Chen, and K. Hayashi, “Preparation of molecularly imprinted polymer nanobeads for selective sensing of carboxylic acid vapors,” Anal Chim Acta, vol. 1010, pp. 1–10, Jun. 2018, doi: 10.1016/j.aca.2018.01.004.

E. V. Piletska, A. R. Guerreiro, M. J. Whitcombe, and S. A. Piletsky, “Influence of the Polymerization Conditions on the Performance of Molecularly Imprinted Polymers,” Macromolecules, vol. 42, no. 14, pp. 4921–4928, Jul. 2009, doi: 10.1021/ma900432z.

E. Yilmaz, K. Mosbach, and K. Haupt, “Influence of functional and cross-linking monomers and the amount of template on the performance of molecularly imprinted polymers in binding assays,” Analytical Communications, vol. 36, no. 5, pp. 167–170, 1999, doi: 10.1039/a901339c.

E. Turiel and A. M. Esteban, “Molecularly imprinted polymers,” in Solid-Phase Extraction, Elsevier, 2020, pp. 215–233. doi: 10.1016/B978-0-12-816906-3.00008-X.

A. N. Hasanah, N. Safitri, A. Zulfa, N. Neli, and D. Rahayu, “Factors Affecting Preparation of Molecularly Imprinted Polymer and Methods on Finding Template-Monomer Interaction as the Key of Selective Properties of the Materials,” Molecules, vol. 26, no. 18, p. 5612, Sep. 2021, doi: 10.3390/molecules26185612.

M. Włoch and J. Datta, “Synthesis and polymerisation techniques of molecularly imprinted polymers,” 2019, pp. 17–40. doi: 10.1016/bs.coac.2019.05.011.

F. Chen, + ; Yang, Z.; Tang, and Y. ; Wang, “Selective Extraction and Determination of Di(2-ethylhexyl) Phthalate in Aqueous Solution by HPLC Coupled with Molecularly Imprinted Solid-phase Extraction,” 2017.

M. I. Malik, H. Shaikh, G. Mustafa, and M. I. Bhanger, “Recent Applications of Molecularly Imprinted Polymers in Analytical Chemistry,” Separation & Purification Reviews, vol. 48, no. 3, pp. 179–219, Jul. 2019, doi: 10.1080/15422119.2018.1457541.

S. Li, Y. Ge, A. Piletsky, and J. Lunec, Molecularly Imprinted Sensors: Overview and Applications, 1st ed., vol. 1. Elsevier, 2021.

G. Vasapollo et al., “Molecularly Imprinted Polymers: Present and Future Prospective,” Int J Mol Sci, vol. 12, no. 9, pp. 5908–5945, Sep. 2011, doi: 10.3390/ijms12095908.

A. Anene, R. Kalfat, Y. Chevalier, and S. Hbaieb, “Design of Molecularly Imprinted Polymeric Materials: The Crucial Choice of Functional Monomers,” Chemistry Africa, vol. 3, no. 3, pp. 769–781, Sep. 2020, doi: 10.1007/s42250-020-00180-1.

L. A. Barros, R. Custodio, and S. Rath, “Design of a New Molecularly Imprinted Polymer Selective for Hydrochlorothiazide Based on Theoretical Predictions Using Gibbs Free Energy,” J Braz Chem Soc, 2016, doi: 10.5935/0103-5053.20160126.

M. Marć and P. P. Wieczorek, “Introduction to MIP synthesis, characteristics and analytical application,” 2019, pp. 1–15. doi: 10.1016/bs.coac.2019.05.010.

L. Chen, X. Wang, W. Lu, X. Wu, and J. Li, “Molecular imprinting: perspectives and applications,” Chem Soc Rev, vol. 45, no. 8, pp. 2137–2211, 2016, doi: 10.1039/C6CS00061D.

F. Shen, Q. Zhang, and X. Ren, “A triple-function zwitterion for preparing water compatible diclofenac imprinted polymers,” Chemical Communications, vol. 51, no. 1, pp. 183–186, 2015, doi: 10.1039/C4CC04739G.

L. Chen, X. Wang, W. Lu, X. Wu, and J. Li, “Molecular imprinting: perspectives and applications,” Chem Soc Rev, vol. 45, no. 8, pp. 2137–2211, 2016, doi: 10.1039/C6CS00061D.

P. Regal, M. Díaz-Bao, R. Barreiro, A. Cepeda, and C. Fente, “Application of molecularly imprinted polymers in food analysis: clean-up and chromatographic improvements,” Open Chem, vol. 10, no. 3, pp. 766–784, Jun. 2012, doi: 10.2478/s11532-012-0016-3.

A. Azizi and C. S. Bottaro, “A critical review of molecularly imprinted polymers for the analysis of organic pollutants in environmental water samples,” J Chromatogr A, vol. 1614, p. 460603, Mar. 2020, doi: 10.1016/j.chroma.2019.460603.

K. Demeestere, M. Petrović, M. Gros, J. Dewulf, H. Van Langenhove, and D. Barceló, “Trace analysis of antidepressants in environmental waters by molecularly imprinted polymer-based solid-phase extraction followed by ultra-performance liquid chromatography coupled to triple quadrupole mass spectrometry,” Anal Bioanal Chem, vol. 396, no. 2, pp. 825–837, Jan. 2010, doi: 10.1007/s00216-009-3270-2.

X. Zhang, S. Xu, Y.-I. Lee, and S. A. Soper, “LED-induced in-column molecular imprinting for solid phase extraction/capillary electrophoresis,” Analyst, vol. 138, no. 10, p. 2821, 2013, doi: 10.1039/c3an00257h.

M. I. Malik, H. Shaikh, G. Mustafa, and M. I. Bhanger, “Recent Applications of Molecularly Imprinted Polymers in Analytical Chemistry,” Separation & Purification Reviews, vol. 48, no. 3, pp. 179–219, Jul. 2019, doi: 10.1080/15422119.2018.1457541.

J. Sardar et al., “Synthesis of Polymerizable Ionic Liquid Monomer and Its Characterization,” IOP Conf Ser Mater Sci Eng, vol. 111, p. 012021, Jan. 2016, doi: 10.1088/1757-899X/111/1/012021.

A. Poma, A. Guerreiro, M. J. Whitcombe, E. V. Piletska, A. P. F. Turner, and S. A. Piletsky, “Solid‐Phase Synthesis of Molecularly Imprinted Polymer Nanoparticles with a Reusable Template–‘Plastic Antibodies,’” Adv Funct Mater, vol. 23, no. 22, pp. 2821–2827, Jun. 2013, doi: 10.1002/adfm.201202397.

R. J. Ansell, “Characterization of the Binding Properties of Molecularly Imprinted Polymers,” 2015, pp. 51–93. doi: 10.1007/10_2015_316.

S. R. Shafqat, S. A. Bhawani, S. Bakhtiar, and M. N. M. Ibrahim, “Synthesis of molecularly imprinted polymer for removal of Congo red,” BMC Chem, vol. 14, no. 1, Apr. 2020, doi: 10.1186/s13065-020-00680-8.

S. R. Shafqat, S. A. Bhawani, S. Bakhtiar, M. N. M. Ibrahim, and S. S. Shafqat, “Template-assisted synthesis of molecularly imprinted polymers for the removal of methyl red from aqueous media,” BMC Chem, vol. 17, no. 1, p. 46, May 2023, doi: 10.1186/s13065-023-00957-8.

S. Arabkhani, S. Pourmoslemi, and A. Larki Harchegani, “Rapid determination of metanil yellow in turmeric using a molecularly imprinted polymer dispersive solid-phase extraction and visible light spectrophotometry,” Food Chem, vol. 380, p. 132120, Jun. 2022, doi: 10.1016/j.foodchem.2022.132120.

M. V. Foguel, N. T. B. Pedro, M. V. B. Zanoni, and M. del P. T. Sotomayor, “Molecularly Imprinted Polymer (MIP): A Promising Recognition System for Development of Optical Sensor for Textile Dyes,” Procedia Technology, vol. 27, pp. 299–300, 2017, doi: 10.1016/j.protcy.2017.04.123.

B. Mortari, S. Khan, A. Wong, R. A. Fireman Dutra, and M. D. P. Taboada Sotomayor, “Next generation of optodes coupling plastic antibody with optical fibers for selective quantification of Acid Green 16,” Sens Actuators B Chem, vol. 305, p. 127553, Feb. 2020, doi: 10.1016/j.snb.2019.127553.

M. Luna Quinto et al., “Development and Characterization of a Molecularly Imprinted Polymer for the Selective Removal of Brilliant Green Textile Dye from River and Textile Industry Effluents,” Polymers (Basel), vol. 15, no. 18, p. 3709, Sep. 2023, doi: 10.3390/polym15183709.

K. Ferchichi, N. Jaoued-Grayaa, J. Kallel, N. Amdouni, Y. Chevalier, and S. Hbaieb, “Selection of the functional monomer for molecularly imprinted polymers based on cellulosic biomaterial for efficient recognition of Brilliant Green,” Polymer Bulletin, vol. 81, no. 11, pp. 9611–9639, Jul. 2024, doi: 10.1007/s00289-024-05161-9.

A. Nematollahzadeh et al., “High‐Capacity Hierarchically Imprinted Polymer Beads for Protein Recognition and Capture,” Angewandte Chemie International Edition, vol. 50, no. 2, pp. 495–498, Jan. 2011, doi: 10.1002/anie.201004774.

I. Chianella, K. Karim, E. V. Piletska, C. Preston, and S. A. Piletsky, “Computational design and synthesis of molecularly imprinted polymers with high binding capacity for pharmaceutical applications-model case: Adsorbent for abacavir,” Anal Chim Acta, vol. 559, no. 1, pp. 73–78, Feb. 2006, doi: 10.1016/j.aca.2005.11.068.

E. N. Ndunda, “Molecularly imprinted polymers—A closer look at the control polymer used in determining the imprinting effect: A mini review,” Journal of Molecular Recognition, vol. 33, no. 11, Nov. 2020, doi: 10.1002/jmr.2855.

Y. Zhang, Z. Xie, X. Teng, and J. Fan, “Synthesis of molecularly imprinted polymer nanoparticles for the fast and highly selective adsorption of sunset yellow,” J Sep Sci, vol. 39, no. 8, pp. 1559–1566, Apr. 2016, doi: 10.1002/jssc.201501295.